Monday, October 5, 2015

TIPS For Thesis studentsL

Tips
An accurate test requires some wise steps.
Such as:
WASHING:

1. Wash your test tubes with soft washing materials like LIQUID VIM.

2. During washing make sure that, there is no sign of residual washing materials like the bubbles/foam of LIQUID VIM, in the equipments. After being confirmed the absence of bubbles/foam, wash it with Distilled Water (DW).VIM Liq 500 ml
DRYING:
3. Completely dry each test tube. Because, as we are dealing with
microgram (μg) of concentration, any residual water even a single drop would change the desired concentration of sample/STD solution.
4. For drying, use hot air oven. In the oven place the equipments to be dried ‘‘invertly”. This will place the opening/mouth of the equipment towards the ground & accordingly the residual debris (if any) would be deposited in the mouth/opening, instead of being in the bottom of that equipment.
5. Never put your hands/figures inside the dried equipments.
MEASURING:
6. Use waxy paper for weighing of the samples, standards, reagents etc.
For an accurate weighing of the solid reagents with normal paper, take 1.2/1.3 mg to weigh 1 mg of solids. Because 0.4/0.3/0.5 mg may adhere to the paper on which you are taking your weights.
MAKING SOLUTION:
7. Use large test tubes (16×150) for 5 ml of total final volume, & small test tubes (12×100) for 3 ml total volume of final solution. Similarly use beakers of various sizes as per requirement of the volume of the solution to be prepared in it.
8. Always mark all the test tubes with their corresponding concentrations as well as the beakers with their corresponding solutions to be prepared in it.
9. If your sample is re-dispersible, then dry the samples (bone dry) in small amount, and re-disperse them after accurate weighing.
10. After taking out any samples, standards, reagents etc from the refrigerator, keep at least 20 minutes in the room temperature before using. Therefore take out them at least 20 minutes before your need.
TAKING ABSORBANCE:
11. Make sure that the absorbance cell is free from all kinds of contamination including residual debris.
12. Take the absorbance from the solutions with the lowest concentration to the solutions with the highest concentration. (i.e. Gradual increment of the test solution concentrations)
13. After taking each absorbance, before proceeding to the next one with different concentrations, if possible ALWAYS  completely discard the residual solutions;
i.e. solutions remaining in the ABSORBANCE CELL.
14. If you have enough test solutions (e.g. more than 3 ml, which may be
5 ml/6ml/7ml) then, range the ABSORBANCE CELL with small volumes of the test solutions having different concentrations in each turn before taking the absorbance of that solution. This will prevent the cross contamination.
15. If Precipitation (PPT) appears, then CENTRIFUGE the solution and use the supernatant layer for taking the absorbance.  You can use micropipettes to withdraw the supernatant layer more conveniently.
16. Generally 2.5 ml (more than 2 ml) of solution in the absorbance cell is enough to take the absorbance.
17. Use new reagents and freshly prepared solvents & solution for each tests.
18. Always use the ‘‘Serial Dilution theory’’ whenever applicable, to make the sample & standard solutions.
pH ADJUSTMENT:
19. If measurements are taken successively in different samples, it is recommended to rinse the electrode thoroughly with de-ionized water or tap water and then with some of the next sample in order to prevent cross-contamination.
20. The pH reading is affected by temperature. In order to measure the pH accurately, the temperature effect must be compensated for. ( For detailed description seeing pH  adjustment manual is mandatory)
CENTRIFUGATION:

Centrifuge Safety GuideF:\♥♥.REASEARCH\Lb Manual\lab manual\fal con tube in centrifuge machine.jpg
Centrifugation may present two serious hazards:
    i. Mechanical failure and
    ii. Dispersion of aerosols.
Therefore this segment would describe safety and maintenance procedures to minimize centrifuge hazards.
Safe Procedures for Centrifugation:
Before centrifugation
------------------------------
  1. Check tubes, bottles, and rotors for cracks and deformities before each use.
  2. Make sure that the rotor, tubes, and spindle are dry and clean.
  3. Never overfill centrifuge tubes (don't exceed ¾ full).
  4. Always cap tubes before centrifugation.
  5. Always balance buckets, tubes, and rotors properly.
  6. Check that the rotor is seated on the drive correctly, close the lid on the centrifuge, and secure it.
  7. When using swinging bucket rotors, make sure that all buckets are hooked correctly and move freely.
During centrifugation
------------------------------
  1. Close lids at all times during operation. Never open a centrifuge until the rotor has stopped.
    F:\♥♥.REASEARCH\Lb Manual\lab manual\670px-Use-a-Centrifuge-Step-2.jpg
  2. Do not exceed safe rotor speed.
  3. The operator should not leave the centrifuge until full operating speed is attained and the machine appears to be running safely without vibration.
  4. Stop the centrifuge immediately if an unusual condition (noise or vibration) begins and check load balances.
After centrifugation
------------------------------
  1. Allow the centrifuge to come to a complete stop before opening.
Emergency Procedures:
Emergency Situations
------------------------------

The following events are considered an emergency:
• If there is a spill in the centrifuge
• If centrifuge malfunctions
• If there is rotor failure
• If there is tube breakage

Emergency Procedures
------------------------------

• Turn centrifuge off immediately, close the centrifuge lid.
• Notify others, evacuate the lab,

Overall, things would be clear to you, during your practical session.

‘’Wishing your very good luck’’ Md. Imran Nur Manik
                imran.md39@gmail.com (+facebook)


Molecular Weights Essentials
Name of the Atom(Symbol)
Mean Relative Atomic Mass

Hydrogen (H
Nitrogen (N)
Oxygen (O)
Sodium (Na)
Phosphorus (P)
Sulphur (S)
Chlorine(Cl)
Potassium (K)
Ferrous(Fe)

1.0079~1
14.0067~14
15.9994~16
22.9897~23
30.9737~31
32.065~32
35.45
39.09983~39.1
55.85

In A Nutshell
Name of the reagents

Molecular Formula

Molecular weight (g/mol)

Ammonium molybdate

[NH4]6Mo7O24.4H2O.

1235.9

Trisodium phosphate; TSP

Na3PO4

163.94

DI-POTASSIUM PHOSPHATE, Potassium Hydrogen Phosphate, Potassium dibasic phosphate, Potassium phosphate dibasic.


K2HO4P



174.18

Potassium acid phosphate

KH2PO4

136.09

Caustic potash; Potash lye

KOH

56.11/56.1056

2-deoxy-L-erythro-pentose;
(3R,4S)-3,4,5-trihydroxypentanal;
L-Deoxyribose


C5H10O4


134.13

Edetate disodium salt dihydrate

C10H14N2Na2O8·2H2O

372.24

Ferric chloride;
Iron trichloride; Molysite


FeCl3


162.20/ 162.204

Oxydol; perhydrol

H2O2

34.01/ 34.01468

Vitamin C;
L-Threoascorbic acid; Antiscorbutic factor


C6H8O6


176.12/ 176.12412

2-Amino-2-(hydroxymethyl)-1,3-propanediol TRIS BASE


C4H11NO3


121.14

Potassium Chloride

KCl

74.55

Iron (III) chloride

FeCl3

162.204

Hydrogen chloride

HCl

36.46

Sodium Hydroxide, Pellets

NaOH

40

5,5′-dithiobis-(2-nitrobenzoic acid)

C14H8N2O8S2

396.35

Sodium Chloride

NaCl

58.44

Magnesium Chloride, Hexahydrate

MgCl2.6H2O

203.30

Acetylthiocholine iodide

C7H16INOS (Linear Formula)
CH3COSCH2CH2N(CH3)3I

289.18/289.17751

S-Butyrylthiocholine iodide

  C9H20INOS  (Linear Formula) (CH3)3N(I)CH2CH2SCOCH2CH2CH3

317.23/ 317.23067






Physical properties of Hydrochloric acid
kg HCl/kg 
kg HCl/m3
Baumé
kg/L
mol/dm3

mPa·s
kJ/(kg·K)
kPa
°C
°C
10%
104.80
6.6
1.048
2.87
−0.5
1.16
3.47
1.95
103
−18
20%
219.60
13
1.098
6.02
−0.8
1.37
2.99
1.40
108
−59
30%
344.70
19
1.149
9.45
−1.0
1.70
2.60
2.13
90
−52
32%
370.88
20
1.159
10.17
−1.0
1.80
2.55
3.73
84
−43
34%
397.46
21
1.169
10.90
−1.0
1.90
2.50
7.24
71
−36
36%
424.44
22
1.179
11.64
−1.1
1.99
2.46
14.5
61
−30
38%
451.82
23
1.189
12.39
−1.1
2.10
2.43
28.3
48
−26


The reference temperature and pressure for the above table are 20 °C and 1 atmosphere (101.325 kPa). Vapour pressure values are taken from the International Critical Tables, and refer to the total vapour pressure of the solution.

N.B.The Baumé scale is a pair of hydrometer scales developed by French pharmacist Antoine Baumé in 1768 to measure density of various liquids.
The Test Reagents
Name of the Reagents (Formulae)
Name of the Reagents (Formulae)
Folin-Ciocalteu Reagent: FCR
Phosphate Buffer (K2HPO4+KH2PO4) pH 6.6
Sodium Carbonate (Na2CO3)
Potassium Ferricyanide :K3Fe(CN)6
Aluminium Chloride (AlCl3)
Trichloro Acetic Acid (TCA)
Sodium Nitrate (NaNO2)
Ferric Chloride (FeCl3)
Soium Hydroxide (NaOH)
2-Deoxy -D- ribose, (C5H10O4)
DPPH
KH2PO4-KOH Buffer :pH 7.4
Sulfuric Acid  (H2SO4)
EDTA
Sodium Phosphate (Na3PO4)
Gallic Acid & Catechin (Standard)
Ammonium Molybdate
Hydrogen Peroxide (H2O2)
Thio-Barbituric Acid (TBA)
Ascorbic Acid,(C6H8O6)
Vanillin


The Test apparatuses
01. Rotary Evaporator
02. UV machine
03. pH meter
04. Vortex Machine
05. Water Bath
06. Centrifuge Machine
07. Electrical Balance
           {3 Digits after the point (0.000g); 4 Digits after the point (0.0000g)}
08. Hot Air Oven
09. Measuring cylinder (25 ml, 100 ml, 500 ml)
10. Beaker (10 ml, 50 ml,100 ml, 250 ml, 500 ml,1000 ml)
11. Test tubes (12×100, 16×150, 16×125)
12. Falcon tubes (15 ml, 50 ml)
13. Eppendrop Tubes
14. Glass rod
15. Spatula
16. Pipettes (1 ml,2 ml,10 ml)
17. Micropipettes (10-100 μl,100-1000 μl)
18. Tips
19. Reagent Bottles
20. Glass Vials
21. Test tube Stands etc.


For Pdf File:https://www.facebook.com/download/644807085660434/tips%20for%20thesis%20students.pdf

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